Materials scientists from Lomonosov Moscow State University explained the laws of dissolution and crystallization of hybrid perovskites and proposed a novel approach for obtaining films for solar cells

Scientists of the Lomonosov Moscow State University, Department Materials Science explained the key mechanisms of interaction of hybrid perovskites with solvents and suggested new approaches to obtain perovskite light-absorbing layers for thin-film solar cells from weakly coordinating aprotic solvents.

The results of the study have been recently published in the high-rating journal Chemistry of Materials.

A team of scientists at the Department of Materials Science and the Department of Chemistry of Lomonosov Moscow State University conducts an intensive work in the field of perovskite photovoltaics, which is now the most rapidly developing area in materials science.

So far, thin-film solar cells based on hybrid perovskites have already reached an efficiency of 23.2%, surpassing traditional solar cells based on silicon. The light-absorbing layer of perovskite in such devices can be obtained by simpler and cheaper solution methods.

In a new study, performed in the laboratory of "New Materials for Solar Energetics" under the supervision of the head of the laboratory, Ph.D. Alexey Tarasov, young scientists studied the processes of perovskite crystallization from a solvent with unusual properties - gamma-butyrolactone (GBL).

"In our laboratory we develop new innovative non-solvent methods for obtaining solar cells but also pay great attention to the fundamental aspects of perovskite chemistry. This is a traditional characteristic trait of the materials science school of Lomonosov Moscow State University, which distinguishes us from most of the world's groups", - said Alexey Tarasov.

There are two solvents which are usually used to prepare perovskite thin films from solutions: dimethylsulfoxide and dimethylformamide. However, our earlier work showed that crystallization from these solvents proceeds through formation of intermediate compounds - crystallosolvates, which can impair the morphology and functional properties of the perovskite layer.

As a solvent for perovskite, GBL has been also known. In particular, it exhibits so-called retrograde solubility (solubility of perovskite in it decreases with the increase of temperature).

This feature was widely used by researchers to produce single crystals, whereas the attempts to obtain a thin film resulted in the formation of separated individual crystallites on a substrate.

For a long time, this unusual behavior of perovskite solutions in GBL has remained obscure. It was believed that the perovskite-GBL interaction is weak enough that it does not even form solvates with it (explain).

However, scientists discovered that there are at least three types of perovskite crystals with GBL, and some of them have a unique cluster structure. It became clear that the equilibrium in perovskite solutions in GBL is much more complicated than previously expected.

"We have established that perovskite dissolves at room temperature with the formation of such clusters, and upon heating they decompose to small complexes. This leads to supersaturation and precipitation of perovskite from solution in the form of single crystals.

"We showed that it was theprecipitation of a cluster adduct instead of perovskite that prevented the formation of thin films from this solvent. Based on the understanding of the processes that occur during the dissolution of perovskite in GBL, we proposed approaches that bypass the formation of clusters and results in perovskite crystallization.

"Consequently, we obtained high-quality films from GBL for the first time. This is an excellent example of the practical application of fundamental chemical knowledge for the solution of materials science problems - just what is generally called fundamental material science throughout the world", - concluded Alexey Tarasov.

Research paper

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