The worldwide quest by researchers to find better, more efficient materials for tomorrow's solar panels is usually slow and painstaking. Researchers typically must produce lab samples - which are often composed of multiple layers of different materials bonded together - for extensive testing.

Now, a team at MIT and other institutions has come up with a way to bypass such expensive and time-consuming fabrication and testing, allowing for a rapid screening of far more variations than would be practical through the traditional approach.

The new process could not only speed up the search for new formulations, but also do a more accurate job of predicting their performance, explains Rachel Kurchin, an MIT graduate student and co-author of a paper describing the new process that appears this week in the journal Joule. Traditional methods "often require you to make a specialized sample, but that differs from an actual cell and may not be fully representative" of a real solar cell's performance, she says.

For example, typical testing methods show the behavior of the "majority carriers," the predominant particles or vacancies whose movement produces an electric current through a material. But in the case of photovoltaic (PV) materials, Kurchin explains, it is actually the minority carriers - those that are far less abundant in the material - that are the limiting factor in a device's overall efficiency, and those are much more difficult to measure.

In addition, typical procedures only measure the flow of current in one set of directions - within the plane of a thin-film material - whereas it's up-down flow that is actually harnessed in a working solar cell. In many materials, that flow can be "drastically different," making it critical to understand in order to properly characterize the material, she says.

"Historically, the rate of new materials development is slow - typically 10 to 25 years," says Tonio Buonassisi, an associate professor of mechanical engineering at MIT and senior author of the paper.

"One of the things that makes the process slow is the long time it takes to troubleshoot early-stage prototype devices," he says.

"Performing characterization takes time - sometimes weeks or months - and the measurements do not always have the necessary sensitivity to determine the root cause of any problems."

So, Buonassisi says, "the bottom line is, if we want to accelerate the pace of new materials development, it is imperative that we figure out faster and more accurate ways to troubleshoot our early-stage materials and prototype devices." And that's what the team has now accomplished. They have developed a set of tools that can be used to make accurate, rapid assessments of proposed materials, using a series of relatively simple lab tests combined with computer modeling of the physical properties of the material itself, as well as additional modeling based on a statistical method known as Bayesian inference.

The system involves making a simple test device, then measuring its current output under different levels of illumination and different voltages, to quantify exactly how the performance varies under these changing conditions. These values are then used to refine the statistical model.

"After we acquire many current-voltage measurements [of the sample] at different temperatures and illumination intensities, we need to figure out what combination of materials and interface variables make the best fit with our set of measurements," Buonassisi explains.

"Representing each parameter as a probability distribution allows us to account for experimental uncertainty, and it also allows us to suss out which parameters are covarying."

The Bayesian inference process allows the estimates of each parameter to be updated based on each new measurement, gradually refining the estimates and homing in ever closer to the precise answer, he says.

In seeking a combination of materials for a particular kind of application, Kurchin says, "we put in all these materials properties and interface properties, and it will tell you what the output will look like."

The system is simple enough that, even for materials that have been less well-characterized in the lab, "we're still able to run this without tremendous computer overhead." And, Kurchin says, making use of the computational tools to screen possible materials will be increasingly useful because "lab equipment has gotten more expensive, and computers have gotten cheaper. This method allows you to minimize your use of complicated lab equipment."

The basic methodology, Buonassisi says, could be applied to a wide variety of different materials evaluations, not just solar cells - in fact, it may apply to any system that involves a computer model for the output of an experimental measurement.

"For example, this approach excels in figuring out which material or interface property might be limiting performance, even for complex stacks of materials like batteries, thermoelectric devices, or composites used in tennis shoes or airplane wings." And, he adds, "It is especially useful for early-stage research, where many things might be going wrong at once."

Going forward, he says, "our vision is to link up this fast characterization method with the faster materials and device synthesis methods we've developed in our lab." Ultimately, he says, "I'm very hopeful the combination of high-throughput computing, automation, and machine learning will help us accelerate the rate of novel materials development by more than a factor of five. This could be transformative, bringing the timelines for new materials-science discoveries down from 20 years to about three to five years."

Research paper

Tweet

Columbia engineers develop floating solar fuels rig for seawater electrolysis
New York, NY (SPX) Dec 28, 2017
In a single hour, more energy from the sun hits the Earth than all the energy used by humankind in an entire year. Imagine if the sun's energy could be harnessed to power energy needs on Earth, and done in a way that is economical, scalable, and environmentally responsible. Researchers have long seen this as one of the grand challenges of the 21st century. Daniel Esposito, assistant profes ... read more

Related Links
Massachusetts Institute of Technology
All About Solar Energy at SolarDaily.com

Thanks for being here; We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor $5 Billed Once credit card or paypal		SpaceDaily Monthly Supporter $5 Billed Monthly paypal only