Solar Energy News  
Novel Gate Dielectric Materials: Perfection Is Not Enough

On the left is an Illustration of the displacement of hafnium atoms (white) in the structure of hafnium oxide to accommodate the presence of the self-trapped hole in the oxygen atom (red). On the right is the quantum mechanics view of the probability of finding a hole near certain atoms (larger blue structures represent higher probability). Credit: London Centre for Nanotechnology
by Staff Writers
London UK (SPX) Oct 17, 2007
For the first time theoretical modeling has provided a glimpse into how promising dielectric materials are able to trap charges, something which may affect the performance of advanced electronic devices. This is revealed in a paper published on the 12th October in Physical Review Letters by researchers at the London Centre for Nanotechnology and SEMATECH, a company in Austin, Texas.

Through the constant quest for miniaturization, transistors and all their components continue to decrease in size. A similar reduction has resulted in the thickness of a component material known as the gate dielectric - typically a thin layer of silicon dioxide, which has now been in use for decades. Unfortunately, as the thickness of the gate dielectric decreases, silicon dioxide begins to leak current, leading to unwieldy power consumption and reduced reliability. Scientists hope that this material can be replaced with others, known as high-dielectric constant (or high-k) dielectrics, which mitigate the leakage effects at these tiny scales.

Metal oxides with high-k have attracted tremendous interest due to their application as novel materials in the latest generation of devices. The impetus for their practical introduction would be further helped if their ability to capture and trap charges and subsequent impact on instability of device performance was better understood. It has long been believed that these charge-trapping properties originate from structural imperfections in materials themselves.

However, as is theoretically demonstrated in this publication, even if the structure of the high k dielectric material is perfect, the charges (either electrons or the absence of electrons - known as holes) may experience 'self trapping'. They do so by forming polarons - a polarizing interaction of an electron or hole with the perfect surrounding lattice. Professor Alexander Shluger of the London Centre for Nanotechnology and the Department of Physics and Astronomy at UCL says: "This creates an energy well which traps the charge, just like a deformation of a thin rubber film traps a billiard ball."

The resulting prediction is that at low temperatures electrons and holes in these materials can move by hopping between trapping sites rather than propagating more conventionally as a wave. This can have important practical implications for the materials' electrical properties. In summary, this new understanding of the polaron formation properties of the transition metal oxides may open the way to suppressing undesirable characteristics in these materials.

Related Links
University College London
London Centre for Nanotechnology
Space Technology News - Applications and Research



Memory Foam Mattress Review
Newsletters :: SpaceDaily :: SpaceWar :: TerraDaily :: Energy Daily
XML Feeds :: Space News :: Earth News :: War News :: Solar Energy News


New Transparent Plastic Strong As Steel
Ann Arbor MI (SPX) Oct 08, 2007
By mimicking a brick-and-mortar molecular structure found in seashells, University of Michigan researchers created a composite plastic that's as strong as steel but lighter and transparent. It's made of layers of clay nanosheets and a water-soluble polymer that shares chemistry with white glue.







  • Putin blames 'worn-out' equipment for Iran nuclear delay
  • Nuclear Deal In Trouble India Warns US As Whitehouse Says Deal Not Dead
  • Nuclear reactors for sale: France vies for big stake in industry revival
  • Estonia completes secure storage facility for Soviet-era reactors

  • Tiny Pacific islands say climate change threatens survival
  • Australian drought pushes up price of beer
  • Heaps Of Climate Gas - Pasturing Cows Convert Soil To A Source Of Methane
  • Gore Nobel win shows up Bush: US press

  • Satellites Help Ensure Efficient Use Of Pesticides
  • Diet With Some Meat Uses Less Land Than Vegetarian Diets
  • Alternative Food Networks Connect Ethical Producers And Consumers, Leads To Healthier Eating
  • Salmonid Hatcheries Cause Stunning Loss Of Reproduction

  • Symposium Marks 30th anniversary Of Discovery Of Third Domain Of Life
  • UD Plant Biologists Uncover Top Wetland Invader's Hidden Weapon
  • Gray Wolves, Grizzly Bears And Bald Eagles - Do They Still Need Protection
  • Life's Hot Spot

  • Jules Verne Dry Cargo Prepared In Turin
  • J-2X Powerpack Test Article Installed On Test Stand
  • Dawn Of A Long Voyage To The Beginning Of Sol And Beyond
  • Kennedy Prepares To Host Constellation Launch Vehicle

  • Nuclear Power In Space - Part 2
  • Outside View: Nuclear future in space
  • Nuclear Power In Space

  • Successful Image Taking By The High Definition Television
  • Boeing Launches WorldView-1 Earth-Imaging Satellite
  • New Faraway Sensors Warn Of Emerging Hurricane's Strength
  • Key Sensor For Northrop Grumman NPOESS Program Passes Critical Structural Test

  • Novel Gate Dielectric Materials: Perfection Is Not Enough
  • Software Overcomes Problems Of Operating Research Tools Over The Internet
  • Stroll virtual world without moving a finger
  • Small is beautiful: Incredible shrinking memory drives new IT

  • The content herein, unless otherwise known to be public domain, are Copyright Space.TV Corporation. AFP and UPI Wire Stories are copyright Agence France-Presse and United Press International. ESA Portal Reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space.TV Corp on any Web page published or hosted by Space.TV Corp. Privacy Statement